This episode shows us some of the friction between Harry and Peter when he decides to join the football team so the flash and Kenny don't end up messing with him but it backfires as usual since when he's playing he's using his spider powers to his advantage but Harry becomes jealous and that forces Peter to stop using his powers and fail at the tryouts. The villain this time is sandman who keeps robbing banks and getting thwarted by spidey and after he's had enough he decides to take him down in the final action sequence in which we see sandman so powers affect spideys powers from his inability to crawl on walls because of sand to his web shooters being utterly useless he has to resort to using mud to freeze sandman in his place and as spidey puts it "build a statue in your honor". One last thing to mention is Gwen showing her affection for Peter but Peter not showing her his feelings it was a great way to show us how she feels after they've hinted at her feelings towards him in previous episodes.
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