Dawn catches, releases, and recatches a Pachirisu. While Pachirisu is released, Jessie tries to catch it, but fails.
The English dub title is a reference to the phrase "Once bitten, twice shy."
Dawn's capture of Pachirisu represents the first time a main character has obtained an Electric-type Pokémon since Ash received Pikachu in Pokemon Kimi ni Kimeta! (1997).
Dub title: Twice Smitten, Once Shy.