John Dehner's character, Colonel Kyle K. Kirby, a Tennessee gentleman who wears a white suit, string tie, and white hat, is a parody of Colonel Sanders of Kentucky Fried Chicken/KFC fame.
The title is a parody on the 1934 song "Stars Fell on Alabama."
The remnants of the "Gilligan's Island" lagoon set are used in this episode
Title is also a riff on a "gaseous word that rhymes with Smart. "F*** Smell over Alabama"