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- Mark and Digger find a decade-old jar of Popcorn Sutton's shine and vow to re-create their mentor's infamous last run; with help from old-timer JB Rader, they rebuild Popcorn's pot still and recount the antics of Appalachia's most legendary outlaw.
- Moonshiners share their tricks for running shine and how they avoid the long arm of the law. Tim reveals a visit with Tickle behind bars, and Mark & Digger reveal an unexpected twist in their search for Popcorn Sutton's shine, stashed a decade ago.
- Mark & Digger build a hillbilly hack to save their handmade vodka. Pam may know more than she thinks about Popcorn's lost shine. Nothing but trouble for Josh running a still outside of the woods. Patti and David risk a seaplane bootleg on the bayou.
- Tickle's back and funnier than ever after a year in jail. Josh, already in stitches, reveals an unexpected twist to his season. Mark and Digger uncover how Popcorn's shine-hoarding ways will pay off for Pam, and Tim gets a rematch on a proofing challenge.
- When Tickle returns to the outlaw side, even Tim can't resist the call of the backwoods. Mark and Digger rediscover a lost recipe from a legend. Mike finds the ultimate secret mountain still site, if only he can build a way to access it.
- Moonshine's prodigal son, Tickle, returns from a year in jail to the Appalachian backwoods. With longtime partner, Tim, determined to stay legal, Tickle recruits an old friend to make an inaugural run of shine and re-stake his claim as an outlaw shiner.
- Tim and Tickle return to the scene of past crimes and rediscover their passion for outlaw moonshining. Mark Rogers designs a custom pot still to double distill shine he can sell for twice the price. Mark and Digger hand-build a copper mailbox still.
- Tickle mashes in his first large scale run of outlaw shine in years. Mark and Digger scramble to save their Popcorn legacy mash from runaway livestock. Mike ditches Daniel for a new full-time partner. Mark and Huck double their proof and their price.
- Mark and Digger attempt their first backwoods miracle, turning wedding cake into moonshine. Tickle scrambles for cover when aerial surveillance threatens a return to jail. And Appalachia's most accident-prone shiner is back operating heavy machinery.
- Josh breaks into his secret stash to build a new still site, and breaks out his shotgun when a drone invades his airspace. Daniel hits the jackpot selling for Mark and Digger, while Mike finds his steady customers mysteriously less thirsty than usual.
- Tim devises a plan to make backwoods shine with Tickle for the first time in years. Short on patience and a key ingredient, Mark and Digger's bootleg operation comes under threat. In a series first, two Tennessee shiners get busted by cops on camera.
- Tickle's carpentry skills shine as Virginia outlaws plan a risky mod to their still. Mark and Digger take a big swing on a small ingredient that can't pass the sniff test. Josh digs deep and uncovers the worst way to foster a toxic work environment.
- Tickle answers the call when Josh needs help salvaging an abandoned submarine still and his season. Mark and Digger take on a specialty bourbon made from Indian corn. Facing jail time, Van and Ewok gamble their freedom for another run.
- Mark and Digger attempt to rescue a former apprentice from a moonshine calamity. An unknown competitor invades Mike's turf, forcing him to change his shine strategy. Mark and Huck bank on backwoods survival skills to fuel their high-proof run.
- Tickle announces his engagement and Tim discovers why his best friend can't quit the outlaw side. Unable to sell any shine, Mike attempts a long-distance bootleg that puts him in the crosshairs of the law. Josh bets that Sin City needs one more vice.
- A young outlaw with an old pot still earns an apprenticeship with Mark and Digger. Mountain man Mark tackles a week-long run to hit an $18K order that includes special delivery. In a desperate attempt to fix his worm barrel, Josh dives in headfirst.
- Tickle and the Laws infuse anxiety-reducing CBD into their shine but the science is anything but stress-free. Josh digs into his secret stash to cure his subterranean blues. A mystery bootlegger dominates Mike's turf and it's about to get incendiary.
- Mike and Jerry confront Daniel about how their rival's liquor is invading their territory. Tickle, Henry and Kenny scale up their CBD-infused moonshine operation. A new bootlegger makes Mark and Digger an offer they can't refuse.