- After the production of That '70s Show (1998) ended, he purchased the '69 Oldsmobile Vista Cruiser used in the show for $500.
- Has been a victim on Punk'd (2003) more often than anyone else.
- Was born in Miami, but moved to Venezuela when he was 3.
- Best friends with Ashton Kutcher.
- Is of Colombian and Venezuelan descent.
- In December 2005, he signed on for a role in the remake of the television show CHiPs (1977). In November 2002, he and That '70s Show (1998) costar Danny Masterson portrayed "Ponch" and "Jon" (respectively) in a Mad TV (1995) skit parodying CHiPs (1977).
- Is fluent in Spanish.
- Is a United Service Organizations (USO) advocate and USO global ambassador. Has had eight USO tours visiting nine international locations (Germany, Poland, South Korea, Afghanistan, Djibouti, Greenland, Norway, Bahrain, Iraq) and a ship at sea; and three domestic locations.
- Has a daughter: Nakano Oceana Valderrama (b. February 15, 2021) with fiancée, Amanda Pacheco.
- Ex-boyfriend of Mandy Moore.
- Ex-boyfriend of Lindsay Lohan.
- Engaged to Amanda Pacheco, a model and PADI (Professional Association of Diving Instructors) divemaster, since January 1 (New Year's Day), 2020.
- Graduated from William Howard Taft Charter High School (Los Angeles, California) in 1999.
- Owns a film and television production company - WV Entertainment, which produces a variety of different programming ranging from animation and scripted series' to docu-follow reality shows.
- Was a guest at Demi Moore and Ashton Kutcher's wedding.
- One of People Magazine's "Top 50 Bachelors" (2002)
- He and Cassandra Scerbo are godparents of Kenneth Carney (b. 2012), son of Tiffany Thornton and her first husband, Chris Carney.
- Resides in Los Angeles, California.
- Close friend of Gia Mantegna.
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