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| Episode cast overview, first billed only: | |||
| Zachary Levi | ... | Chuck Bartowski | |
| Yvonne Strahovski | ... | Sarah Walker | |
| Joshua Gomez | ... | Morgan Grimes | |
| Ryan McPartlin | ... | Devon 'Captain Awesome' Woodcomb | |
| Mark Christopher Lawrence | ... | Big Mike (credit only) | |
| Vik Sahay | ... | Lester Patel | |
| Scott Krinsky | ... | Jeff Barnes | |
| Sarah Lancaster | ... | Ellie Bartowski | |
| Adam Baldwin | ... | John Casey | |
| Bonita Friedericy | ... | General Diane Beckman | |
| Carlos Lacamara | ... | Juan Diego Arnaldo | |
| Lela Loren | ... | Elia | |
| Ian Patrick Williams | ... | Mustache Man | |
| Jack Guzman | ... | Drugged Interpol Agent #1 | |
| Nico Cortez | ... | Interpol Agent #1 | |
Chuck and Sara have deserted to lead 'normal' lives as a couple, but the 'honeymooners' find themselves on a Swiss train with ETA cell commander Juan Diego Arnaldo. The men they assumed his accomplices are actually Interpol informer minders, but real terrorist lurk too. The general allows Casey to rejoin as ideal rescue mission leader, assisted only by Grimes. Meanwhile Devon gets stuck with Jeffster and can barely control Ellie's emotions when Chuck misses their send-off party before a year in Africa. Written by KGF Vissers
This show seems to be hitting its stride. It's a new dawn and " it's about damn time". I'm feeling good, great show. Alias meets Friends.