| Episode cast overview, first billed only: | |||
| Zachary Levi | ... | Chuck Bartowski | |
| Yvonne Strahovski | ... | Sarah Walker | |
| Joshua Gomez | ... | Morgan Grimes | |
| Ryan McPartlin | ... | Devon 'Captain Awesome' Woodcomb | |
| Mark Christopher Lawrence | ... | Big Mike | |
| Vik Sahay | ... | Lester Patel | |
| Julia Ling | ... | Anna Wu | |
| Scott Krinsky | ... | Jeff Barnes | |
| Sarah Lancaster | ... | Ellie Bartowski | |
| Adam Baldwin | ... | John Casey | |
| John Larroquette | ... | Roan Montgomery | |
| Bonita Friedericy | ... | General Diane Beckman | |
| Matt Bomer | ... | Bryce Larkin (as Matthew Bomer) | |
| Melinda Clarke | ... | Sasha Banacheck | |
| Matthew Jayson Cwern | ... | Handsome Cool Guy (as Matthew Jay Cwern) | |
The team learns that the real part for the Intersect has been stolen. They track down a legendary spy who can train Chuck to get close to the woman who has stolen it. Devin tries to plan a romantic evening for Ellie, and Lester let's his new job go to his head causing some issues at work. Written by Jesse Sanchez