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| Episode cast overview, first billed only: | |||
| Zachary Levi | ... | Chuck Bartowski | |
| Yvonne Strahovski | ... | Sarah Walker | |
| Joshua Gomez | ... | Morgan Grimes | |
| Sarah Lancaster | ... | Ellie Bartowski | |
| Adam Baldwin | ... | John Casey | |
| C.S. Lee | ... | Harry Tang | |
| Bonita Friedericy | ... | General Diane Beckman | |
| Tony Todd | ... | CIA Director Graham | |
| Lorena Bernal | ... | La Ciudad-Malena | |
| Neil Dickson | ... | MI-6 Agent | |
| Grant Thompson | ... | Allan Watterman | |
| Ryan McPartlin | ... | Devon 'Captain Awesome' Woodcomb | |
| Mark Christopher Lawrence | ... | Big Mike | |
| Vik Sahay | ... | Lester Patel | |
| Scott Krinsky | ... | Jeff Barnes | |
Now deprogramming Chuck is off, he gets a first, apparently easy mission, locating stolen art. But it leads to redoubted, elusive arms dealer La Ciudad, who will be at a ball, so he takes tango lessons from Awesome. Meanwhile Casey and Sarah still deeply distrust each-other, each taking a cover job at Buy More and wriggling in at Bartowski home events. Written by KGF Vissers