James was previously married to Oscar-winning actress Sandra Bullock, but the pair split after James cheated. He spills details of the relationship and his troubled upbringing in the memoir "American Outlaw."
He was also married to porn star Janine Lindemulder, with whom he has a daughter, and Karla James, with whom he has two children. He was engaged to Kat Von D in 2011, but the two split up in September.
His most recently rumored bride-to-be is also the daughter of John Paul DeJoria, the co-founder of Paul Mitchell.