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The poisoned cup was by Chuck in the first place. What Chuck does is switch the sugar marker, fooling Patricia into thinking he spun the entire tray. (This means that the poisoned cup is still by Chuck.) She takes the bait, spins the entire tray, and repositions the sugar to where she thinks Chuck won't notice. But because she's the first to actually spin the tray, the poisoned cup is now in front of her.
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