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It does not appear to be hurting Hercules when they force fed the potion to him. However he did cry when the rubber nipple was forcefully taken out of his mouth.
No one knows for sure. It can be speculated that if the baby sucked on it then the spikes on the nipple would have hurt his mouth by pricking his gums and tongue.
While not explained in the movie there could be interpretations that Hades was too busy or ignorant to know about the life status of Hercules. After hearing news-report from his minions Pain and Panic he would presumably be much calmer to wait for the day when he could release the titans where his brother Zeus imprisoned.
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