11 February 2013 10:19 AM, PST | TVLine.com | See recent TVLine.com news »

Disney Xd’s Ultimate Spider-Man will for the first time ever summon The Sinister Six for its next episode, airing Sunday, Feb. 17 at 11 am Est, and TVLine has a first look at all half-dozen baddies — including the thus-far-secret sixth member.

As seen in this exclusive image from “The Sinister Six,” the Doctor is in — as in Doctor Octopus aka Doc Ock, voiced by SpongeBob Squarepants frontman Tom Kenny.

Photo | Jesse Spencer on Disney’s Phineas and Ferb = Not a G’Day for Perry

The überappendaged mad scientist will ally with Kraven The Hunter (voiced by Diedrich Bader), Rhino (Daryl Sabara »

- Matt Webb Mitovich

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