Ricky teamed up with his Kaiser Chiefs bandmate Simon Rix to record the song for the puppet duo's upcoming Cbbc return.
Written by original creators Ciarán Morrison and Mick O'Hara - who also voice the titular characters - the new Zig & Zag show will follow the pair as they wreak havoc in the suburbs after crash landing on Earth.
Coronation Street star Debra Stephenson is also involved in the series, which will run for 26 episodes next spring.
Zig and Zag have been around for absolutely ages, having made their debut on Irish TV way back in 1987.
UK viewers will remember them from The Big Breakfast back in the 90s, and more recently on Big Brother's Little Brother in 2010.
They had number one singles in Ireland,